Paper | Title | Page |
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TUPTB004 | Progress on Zirconium-Doped Niobium Surfaces | 398 |
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Funding: This work was supported by the NSF under Award PHY-1549132, the Center for Bright Beams, and in part by CNF (NSF Grant NNCI-2025233), and in part by CCMR (DMR-1719875). The first experimental studies of zirconium-doped surfaces verified that zirconium can enhance the critical temperature of the surface, resulting in a lower BCS resistance than standard-recipe niobium. However, they also produced a disordered oxide layer, resulting in a higher residual resistance than standard-recipe niobium. Here, we show that zirconium-doped surfaces can grow well-behaved thin oxide layers, with a very thin ternary suboxide capped by a passivating ZrO2 surface. The elimination of niobium pentoxide may allow zirconium-doped surfaces to achieve low residual resistance. |
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DOI • | reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUPTB004 | |
About • | Received ※ 30 June 2023 — Revised ※ 26 July 2023 — Accepted ※ 19 August 2023 — Issue date ※ 22 August 2023 | |
Cite • | reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml) | |
TUPTB006 | Materials Design for Superconducting RF Cavities: Electroplating Sn, Zr, and Au onto Nb and and Chemical Vapor Deposition | 401 |
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Funding: This work was supported by the U.S. National Science Foundation under Award PHY-1549132, the Center for Bright Beams. Materials scientists seek to contribute to the development of next-generation superconducting radio-frequency (SRF) accelerating cavities. Here, we summarize our achievements and learnings in designing advanced SRF materials and surfaces, including Nb₃Sn [1¿3], ZrNb(CO) [4, 5], and Au/Nb surface design [6,7]. Our efforts involve electrochemical synthesis, phase transformation, and surface chemistry, which are closely coupled with superconducting properties, SRF performance, and engineering considerations. We develop electrochemical processes for Sn, Zr, and Au on the Nb surface, an essential step in our investigation for producing high-quality Nb₃Sn, ZrNb(CO), and Au/Nb structures. Additionally, we design a custom chemical vapor deposition system to offer additional growth options. Notably, we find the second-phase NbC formation in ZrNb(CO) and in ultra-high-vacuum baked or nitrogen-processed Nb. We also identify low-dielectric-loss ZrO2 on Nb and NbZr(CO) surfaces. These advancements provide materials science approaches dealing with fundamental and technical challenges to build high-performance, multi-scale, robust SRF cavities for particle accelerators and quantum applications. |
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DOI • | reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUPTB006 | |
About • | Received ※ 30 June 2023 — Revised ※ 11 August 2023 — Accepted ※ 20 August 2023 — Issue date ※ 21 August 2023 | |
Cite • | reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml) | |