SRF2023 - List of Authors (Oseroff, T.E.)

Paper	Title	Page
MOPMB076	Surface Characterization Studies of Gold-Plated Niobium	290
SUSPB024	use link to see paper's listing under its alternate paper code
	S.G. Seddon-Stettler, M. Liepe, T.E. Oseroff, Z. Sun Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA N. Sitaraman Cornell University, Ithaca, New York, USA
	Funding: The National Science Foundation, Grant No. PHY-1549132 The native niobium oxide layer present on niobium has been shown to affect the performace of superconducting RF cavities. Extremely thin layers of gold on the surface of niobium have the potential to suppress surface oxidation and improve cavity performance. However, depositing uniform layers of gold at the desired thickness (sub-nm) is difficult, and different deposition methods may have different effects on the gold surface, on the niobium surface, and on the interface between the two. In particular, the question of whether gold deposition actually passivates the niobium oxide is extremely relevant for assessing the potential of gold deposition to improve RF performance. This work builds on previous research studying the RF performance of gold/niobium bilayers with different gold layer thicknesses. We here consider alternative methods to characterize the composition and chemical properties of gold/niobium bilayers to supplement the previous RF study.
	Poster MOPMB076 [1.536 MB]
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2023-MOPMB076
About •	Received ※ 25 June 2023 — Revised ※ 27 June 2023 — Accepted ※ 29 June 2023 — Issue date ※ 03 July 2023
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

TUIBA01	A Three-Fluid Model of Dissipation at Surfaces in Superconducting Radiofrequency Cavities	361
	M.M. Kelley, T. Arias, S. Deyo, D. Liarte, J.P. Sethna, N. Sitaraman Cornell University, Ithaca, New York, USA M. Liepe, T.E. Oseroff Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA
	Funding: This work was supported by the U.S. National Science Foundation under Award PHY-1549132, the Center for Bright Beams. Experiments on superconducting cavities have found that under large RF fields the quality factor can improve with increasing field amplitude, a so-called anti-Q slope. We numerically solve the Bogoliubov-de Gennes equations at a superconducting surface in a parallel magnetic field, finding at large fields there are surface quasiparticle states with energies below the bulk superconducting gap that emerge and disappear as the field cycles. Modifying the standard two-fluid model, we introduce a ‘‘three’’-fluid model where we partition the normal fluid to consider continuum and surface quasiparticle states separately. We compute dissipation in a semi-classical theory of conductivity, where we provide physical estimates of elastic scattering times of Bogoliubov quasiparticles with point-like impurities having potential strengths informed from complementary ab initio calculations of impurities in bulk niobium. We show, in this simple yet effective framework, how the relative scattering rates of surface and continuum quasiparticle states can play a role in producing an anti-Q slope while demonstrating how this model naturally includes a mechanism for turning the anti-Q slope on and off. S. Deyo, M. Kelley et al. Phys. Rev. B 106, 104502 (2022)
	Slides TUIBA01 [2.019 MB]
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUIBA01
About •	Received ※ 19 June 2023 — Revised ※ 23 June 2023 — Accepted ※ 28 June 2023 — Issue date ※ 08 July 2023
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

TUCBA01	Measurements of the Amplitude-Dependent Microwave Surface Resistance of a Proximity-Coupled Au/Nb Bilayer	369
	T.E. Oseroff, M. Liepe, Z. Sun Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA
	A sample host cavity is used to measure the surface resistance of a niobium substrate with a gold film deposited in place of its surface oxide. This talk will report about this measurement result. The film thickness of the gold layer was increased from 0.1 nm to 2.0 nm in five steps to study the impact of the normal layer thickness. The 0.1 nm film was found to reduce the surface resistance below its value with the surface oxide present and to enhance the quench field. The magnitude of the surface resistance increased substantially with gold film thickness. The surface resistance field-dependence appeared to be independent from the normal layer thickness. The observations reported in this work have profound implications for both low-field and high-field S.C. microwave devices. By controlling or eliminating the niobium oxide using a gold layer to passivate the niobium surface, it may be possible to improve the performance of SRF cavities used for particle acceleration. This method to reduce surface oxidation while maintaining low surface resistance could also be relevant for minimizing dissipation due to two-level systems observed in low-field low-temperature devices.
	Slides TUCBA01 [2.292 MB]
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUCBA01
About •	Received ※ 19 June 2023 — Revised ※ 29 June 2023 — Accepted ※ 30 June 2023 — Issue date ※ 26 July 2023
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

TUPTB004	Progress on Zirconium-Doped Niobium Surfaces	398
	N. Sitaraman, T. Arias, Z. Baraissov, D.A. Muller Cornell University, Ithaca, New York, USA G. Gaitan, M. Liepe, T.E. Oseroff, Z. Sun Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA
	Funding: This work was supported by the NSF under Award PHY-1549132, the Center for Bright Beams, and in part by CNF (NSF Grant NNCI-2025233), and in part by CCMR (DMR-1719875). The first experimental studies of zirconium-doped surfaces verified that zirconium can enhance the critical temperature of the surface, resulting in a lower BCS resistance than standard-recipe niobium. However, they also produced a disordered oxide layer, resulting in a higher residual resistance than standard-recipe niobium. Here, we show that zirconium-doped surfaces can grow well-behaved thin oxide layers, with a very thin ternary suboxide capped by a passivating ZrO2 surface. The elimination of niobium pentoxide may allow zirconium-doped surfaces to achieve low residual resistance.
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUPTB004
About •	Received ※ 30 June 2023 — Revised ※ 26 July 2023 — Accepted ※ 19 August 2023 — Issue date ※ 22 August 2023
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

TUPTB006	Materials Design for Superconducting RF Cavities: Electroplating Sn, Zr, and Au onto Nb and and Chemical Vapor Deposition	401
	Z. Sun, M. Liepe, T.E. Oseroff Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA Z. Baraissov, D.A. Muller, M.O. Thompson Cornell University, Ithaca, USA
	Funding: This work was supported by the U.S. National Science Foundation under Award PHY-1549132, the Center for Bright Beams. Materials scientists seek to contribute to the development of next-generation superconducting radio-frequency (SRF) accelerating cavities. Here, we summarize our achievements and learnings in designing advanced SRF materials and surfaces, including Nb₃Sn [1¿3], ZrNb(CO) [4, 5], and Au/Nb surface design [6,7]. Our efforts involve electrochemical synthesis, phase transformation, and surface chemistry, which are closely coupled with superconducting properties, SRF performance, and engineering considerations. We develop electrochemical processes for Sn, Zr, and Au on the Nb surface, an essential step in our investigation for producing high-quality Nb₃Sn, ZrNb(CO), and Au/Nb structures. Additionally, we design a custom chemical vapor deposition system to offer additional growth options. Notably, we find the second-phase NbC formation in ZrNb(CO) and in ultra-high-vacuum baked or nitrogen-processed Nb. We also identify low-dielectric-loss ZrO2 on Nb and NbZr(CO) surfaces. These advancements provide materials science approaches dealing with fundamental and technical challenges to build high-performance, multi-scale, robust SRF cavities for particle accelerators and quantum applications.
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUPTB006
About •	Received ※ 30 June 2023 — Revised ※ 11 August 2023 — Accepted ※ 20 August 2023 — Issue date ※ 21 August 2023
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

WEIAA04	Development of High-performance Niobium-3 Tin Cavities at Cornell University	600
	L. Shpani, S.G. Arnold, G. Gaitan, M. Liepe, T.E. Oseroff, R.D. Porter, N.A. Stilin, Z. Sun, N.M. Verboncoeur Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA N. Sitaraman Cornell University, Ithaca, New York, USA
	Funding: Work supported by the National Science Foundation under Grant No. PHY-1549132, the Center for Bright Beam and U.S. DOE grant No. DE-SC0008431. Niobium-3 tin is a promising material for next-generation superconducting RF cavities due to its high critical temperature and high theoretical field limit. There is currently significant worldwide effort aiming to improve Nb₃Sn growth to push this material to its ultimate performance limits. This talk will present an overview of Nb₃Sn cavity development at Cornell University. One approach we are pursuing is to further advance the vapor diffusion process through optimized nucleation and film thickness. Additionally, we are exploring alternative Nb₃Sn growth methods, such as the development of a plasma-enhanced chemical vapor deposition (CVD) system, as well as Nb₃Sn growth via electrochemical synthesis.
	Slides WEIAA04 [5.260 MB]
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2023-WEIAA04
About •	Received ※ 29 June 2023 — Revised ※ 11 August 2023 — Accepted ※ 21 August 2023 — Issue date ※ 22 August 2023
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

WEPWB108	Update on Cornell High Pulsed Power Sample Host Cavity	841
SUSPB029	use link to see paper's listing under its alternate paper code
	N.M. Verboncoeur, A.T. Holic, M. Liepe, T.E. Oseroff, R.D. Porter, J. Sears, L. Shpani Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA R.D. Porter SLAC, Menlo Park, California, USA
	The Cornell High Pulsed Power Sample Host Cavity (CHPPSHC) is designed to measure the temperature-dependent superheating fields of future SRF materials and thereby gain insights into the ultimate limits of their performance. Theoretical estimation of the superheating fields of SRF materials is challenging and mostly has been done for temperatures near the critical temperature or in the infinite kappa limit. Experimental data currently available is incomplete, and often impacted by material defects and their resulting thermal heating, preventing finding the fundamental limits of theses materials. The CHPPSHC system allows reaching RF fields in excess of half a Tesla within microseconds on material samples by utilizing high pulsed power, thereby outrunning thermal effects. We are principally interested in the superheating field of Nb₃Sn, a material of interest for the SRF community, and present here the current fabrication and assembly status of the CHPPSHC as well as early results.
DOI •	reference for this paper ※ doi:10.18429/JACoW-SRF2023-WEPWB108
About •	Received ※ 27 June 2023 — Revised ※ 20 July 2023 — Accepted ※ 20 August 2023 — Issue date ※ 22 August 2023
Cite •	reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

Paper

Title

Page

MOPMB076

Surface Characterization Studies of Gold-Plated Niobium

290

SUSPB024

use link to see paper's listing under its alternate paper code

S.G. Seddon-Stettler, M. Liepe, T.E. Oseroff, Z. Sun
Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA
N. Sitaraman
Cornell University, Ithaca, New York, USA

Funding: The National Science Foundation, Grant No. PHY-1549132
The native niobium oxide layer present on niobium has been shown to affect the performace of superconducting RF cavities. Extremely thin layers of gold on the surface of niobium have the potential to suppress surface oxidation and improve cavity performance. However, depositing uniform layers of gold at the desired thickness (sub-nm) is difficult, and different deposition methods may have different effects on the gold surface, on the niobium surface, and on the interface between the two. In particular, the question of whether gold deposition actually passivates the niobium oxide is extremely relevant for assessing the potential of gold deposition to improve RF performance. This work builds on previous research studying the RF performance of gold/niobium bilayers with different gold layer thicknesses. We here consider alternative methods to characterize the composition and chemical properties of gold/niobium bilayers to supplement the previous RF study.

Poster MOPMB076 [1.536 MB]

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2023-MOPMB076

About •

Received ※ 25 June 2023 — Revised ※ 27 June 2023 — Accepted ※ 29 June 2023 — Issue date ※ 03 July 2023

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

TUIBA01

A Three-Fluid Model of Dissipation at Surfaces in Superconducting Radiofrequency Cavities

361

M.M. Kelley, T. Arias, S. Deyo, D. Liarte, J.P. Sethna, N. Sitaraman
Cornell University, Ithaca, New York, USA
M. Liepe, T.E. Oseroff
Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA

Funding: This work was supported by the U.S. National Science Foundation under Award PHY-1549132, the Center for Bright Beams.
Experiments on superconducting cavities have found that under large RF fields the quality factor can improve with increasing field amplitude, a so-called anti-Q slope. We numerically solve the Bogoliubov-de Gennes equations at a superconducting surface in a parallel magnetic field, finding at large fields there are surface quasiparticle states with energies below the bulk superconducting gap that emerge and disappear as the field cycles. Modifying the standard two-fluid model, we introduce a ‘‘three’’-fluid model where we partition the normal fluid to consider continuum and surface quasiparticle states separately. We compute dissipation in a semi-classical theory of conductivity, where we provide physical estimates of elastic scattering times of Bogoliubov quasiparticles with point-like impurities having potential strengths informed from complementary ab initio calculations of impurities in bulk niobium. We show, in this simple yet effective framework, how the relative scattering rates of surface and continuum quasiparticle states can play a role in producing an anti-Q slope while demonstrating how this model naturally includes a mechanism for turning the anti-Q slope on and off.
S. Deyo, M. Kelley et al. Phys. Rev. B 106, 104502 (2022)

Slides TUIBA01 [2.019 MB]

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUIBA01

About •

Received ※ 19 June 2023 — Revised ※ 23 June 2023 — Accepted ※ 28 June 2023 — Issue date ※ 08 July 2023

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

TUCBA01

Measurements of the Amplitude-Dependent Microwave Surface Resistance of a Proximity-Coupled Au/Nb Bilayer

369

T.E. Oseroff, M. Liepe, Z. Sun
Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA

A sample host cavity is used to measure the surface resistance of a niobium substrate with a gold film deposited in place of its surface oxide. This talk will report about this measurement result. The film thickness of the gold layer was increased from 0.1 nm to 2.0 nm in five steps to study the impact of the normal layer thickness. The 0.1 nm film was found to reduce the surface resistance below its value with the surface oxide present and to enhance the quench field. The magnitude of the surface resistance increased substantially with gold film thickness. The surface resistance field-dependence appeared to be independent from the normal layer thickness. The observations reported in this work have profound implications for both low-field and high-field S.C. microwave devices. By controlling or eliminating the niobium oxide using a gold layer to passivate the niobium surface, it may be possible to improve the performance of SRF cavities used for particle acceleration. This method to reduce surface oxidation while maintaining low surface resistance could also be relevant for minimizing dissipation due to two-level systems observed in low-field low-temperature devices.

Slides TUCBA01 [2.292 MB]

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUCBA01

About •

Received ※ 19 June 2023 — Revised ※ 29 June 2023 — Accepted ※ 30 June 2023 — Issue date ※ 26 July 2023

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

TUPTB004

Progress on Zirconium-Doped Niobium Surfaces

398

N. Sitaraman, T. Arias, Z. Baraissov, D.A. Muller
Cornell University, Ithaca, New York, USA
G. Gaitan, M. Liepe, T.E. Oseroff, Z. Sun
Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA

Funding: This work was supported by the NSF under Award PHY-1549132, the Center for Bright Beams, and in part by CNF (NSF Grant NNCI-2025233), and in part by CCMR (DMR-1719875).
The first experimental studies of zirconium-doped surfaces verified that zirconium can enhance the critical temperature of the surface, resulting in a lower BCS resistance than standard-recipe niobium. However, they also produced a disordered oxide layer, resulting in a higher residual resistance than standard-recipe niobium. Here, we show that zirconium-doped surfaces can grow well-behaved thin oxide layers, with a very thin ternary suboxide capped by a passivating ZrO2 surface. The elimination of niobium pentoxide may allow zirconium-doped surfaces to achieve low residual resistance.

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUPTB004

About •

Received ※ 30 June 2023 — Revised ※ 26 July 2023 — Accepted ※ 19 August 2023 — Issue date ※ 22 August 2023

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

TUPTB006

Materials Design for Superconducting RF Cavities: Electroplating Sn, Zr, and Au onto Nb and and Chemical Vapor Deposition

401

Z. Sun, M. Liepe, T.E. Oseroff
Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA
Z. Baraissov, D.A. Muller, M.O. Thompson
Cornell University, Ithaca, USA

Funding: This work was supported by the U.S. National Science Foundation under Award PHY-1549132, the Center for Bright Beams.
Materials scientists seek to contribute to the development of next-generation superconducting radio-frequency (SRF) accelerating cavities. Here, we summarize our achievements and learnings in designing advanced SRF materials and surfaces, including Nb₃Sn [1¿3], ZrNb(CO) [4, 5], and Au/Nb surface design [6,7]. Our efforts involve electrochemical synthesis, phase transformation, and surface chemistry, which are closely coupled with superconducting properties, SRF performance, and engineering considerations. We develop electrochemical processes for Sn, Zr, and Au on the Nb surface, an essential step in our investigation for producing high-quality Nb₃Sn, ZrNb(CO), and Au/Nb structures. Additionally, we design a custom chemical vapor deposition system to offer additional growth options. Notably, we find the second-phase NbC formation in ZrNb(CO) and in ultra-high-vacuum baked or nitrogen-processed Nb. We also identify low-dielectric-loss ZrO2 on Nb and NbZr(CO) surfaces. These advancements provide materials science approaches dealing with fundamental and technical challenges to build high-performance, multi-scale, robust SRF cavities for particle accelerators and quantum applications.

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2023-TUPTB006

About •

Received ※ 30 June 2023 — Revised ※ 11 August 2023 — Accepted ※ 20 August 2023 — Issue date ※ 21 August 2023

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

WEIAA04

Development of High-performance Niobium-3 Tin Cavities at Cornell University

600

L. Shpani, S.G. Arnold, G. Gaitan, M. Liepe, T.E. Oseroff, R.D. Porter, N.A. Stilin, Z. Sun, N.M. Verboncoeur
Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA
N. Sitaraman
Cornell University, Ithaca, New York, USA

Funding: Work supported by the National Science Foundation under Grant No. PHY-1549132, the Center for Bright Beam and U.S. DOE grant No. DE-SC0008431.
Niobium-3 tin is a promising material for next-generation superconducting RF cavities due to its high critical temperature and high theoretical field limit. There is currently significant worldwide effort aiming to improve Nb₃Sn growth to push this material to its ultimate performance limits. This talk will present an overview of Nb₃Sn cavity development at Cornell University. One approach we are pursuing is to further advance the vapor diffusion process through optimized nucleation and film thickness. Additionally, we are exploring alternative Nb₃Sn growth methods, such as the development of a plasma-enhanced chemical vapor deposition (CVD) system, as well as Nb₃Sn growth via electrochemical synthesis.

Slides WEIAA04 [5.260 MB]

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2023-WEIAA04

About •

Received ※ 29 June 2023 — Revised ※ 11 August 2023 — Accepted ※ 21 August 2023 — Issue date ※ 22 August 2023

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)

WEPWB108

Update on Cornell High Pulsed Power Sample Host Cavity

841

SUSPB029

use link to see paper's listing under its alternate paper code

N.M. Verboncoeur, A.T. Holic, M. Liepe, T.E. Oseroff, R.D. Porter, J. Sears, L. Shpani
Cornell University (CLASSE), Cornell Laboratory for Accelerator-Based Sciences and Education, Ithaca, New York, USA
R.D. Porter
SLAC, Menlo Park, California, USA

The Cornell High Pulsed Power Sample Host Cavity (CHPPSHC) is designed to measure the temperature-dependent superheating fields of future SRF materials and thereby gain insights into the ultimate limits of their performance. Theoretical estimation of the superheating fields of SRF materials is challenging and mostly has been done for temperatures near the critical temperature or in the infinite kappa limit. Experimental data currently available is incomplete, and often impacted by material defects and their resulting thermal heating, preventing finding the fundamental limits of theses materials. The CHPPSHC system allows reaching RF fields in excess of half a Tesla within microseconds on material samples by utilizing high pulsed power, thereby outrunning thermal effects. We are principally interested in the superheating field of Nb₃Sn, a material of interest for the SRF community, and present here the current fabrication and assembly status of the CHPPSHC as well as early results.

DOI •

reference for this paper ※ doi:10.18429/JACoW-SRF2023-WEPWB108

About •

Received ※ 27 June 2023 — Revised ※ 20 July 2023 — Accepted ※ 20 August 2023 — Issue date ※ 22 August 2023

Cite •

reference for this paper using ※ BibTeX, ※ LaTeX, ※ Text/Word, ※ RIS, ※ EndNote (xml)